Ohyun Kwon

Title(s)Professor, Chemistry and Biochemistry
SchoolCollege of Letters and Science
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    Collapse Research 
    Collapse Research Activities and Funding
    Deconstructive Molecular Editing Technology Involving C-C Bond Scission
    NIH R01GM141327Apr 1, 2021 - Dec 31, 2024
    Role: Principal Investigator
    Pilot-Scale Library Production Based on Phosphine Catalysis of Allenes
    NIH P41GM081282Sep 4, 2007 - Aug 31, 2011
    Role: Principal Investigator
    Phosphine-Catalyzed Annulations and their Applications
    NIH R01GM071779May 1, 2006 - Jun 30, 2022
    Role: Principal Investigator

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    Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications. Researchers can login to make corrections and additions, or contact us for help. to make corrections and additions.
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    1. Phosphorus-Based Catalysis. ACS Cent Sci. 2021 Apr 28; 7(4):536-558. Xie C, Smaligo AJ, Song XR, Kwon O. PMID: 34056085; PMCID: PMC8155461.
      View in: PubMed   Mentions: 6  
    2. Unified Approach to Furan Natural Products via Phosphine-Palladium Catalysis. Angew Chem Int Ed Engl. 2021 04 12; 60(16):8874-8881. Chen VY, Kwon O. PMID: 33533120; PMCID: PMC8016739.
      View in: PubMed   Mentions: 2     Fields:    Translation:Cells
    3. Dealkenylative Alkenylation: Formal σ-Bond Metathesis of Olefins. Angew Chem Int Ed Engl. 2020 09 28; 59(40):17565-17571. Swain M, Sadykhov G, Wang R, Kwon O. PMID: 32652746; PMCID: PMC8232059.
      View in: PubMed   Mentions: 1     Fields:    Translation:Cells
    4. Phosphine-Catalyzed (4+1) Annulation: Rearrangement of Allenylic Carbamates to 3-Pyrrolines through Phosphonium Diene Intermediates. ChemCatChem. 2020 Sep 04; 12(17):4352-4372. Blank BR, Andrews IP, Kwon O. PMID: 34447481; PMCID: PMC8386297.
      View in: PubMed   Mentions: 1  
    5. Oxodealkenylative Cleavage of Alkene C(sp3 )-C(sp2 ) Bonds: A Practical Method for Introducing Carbonyls into Chiral Pool Materials. Angew Chem Int Ed Engl. 2020 Jan 13; 59(3):1211-1215. Smaligo AJ, Wu J, Burton NR, Hacker AS, Shaikh AC, Quintana JC, Wang R, Xie C, Kwon O. PMID: 31692203; PMCID: PMC6942233.
      View in: PubMed   Mentions: 3     Fields:    
    6. Dealkenylative Thiylation of C(sp3)-C(sp2) Bonds. Org Lett. 2019 11 01; 21(21):8592-8597. Smaligo AJ, Kwon O. PMID: 31573208; PMCID: PMC7337987.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    7. Phosphine-Catalyzed α-Umpolung-Aldol Reaction for the Synthesis of Benzo[ b]azapin-3-ones. Org Lett. 2019 07 05; 21(13):5143-5146. Zhang K, Cai L, Hong S, Kwon O. PMID: 31247774; PMCID: PMC7338222.
      View in: PubMed   Mentions: 2     Fields:    Translation:Cells
    8. Catalytic Asymmetric Staudinger-aza-Wittig Reaction for the Synthesis of Heterocyclic Amines. J Am Chem Soc. 2019 06 19; 141(24):9537-9542. Cai L, Zhang K, Chen S, Lepage RJ, Houk KN, Krenske EH, Kwon O. PMID: 31184143; PMCID: PMC7371345.
      View in: PubMed   Mentions: 9     Fields:    Translation:Cells
    9. Hydrodealkenylative C(sp3)-C(sp2) bond fragmentation. Science. 2019 05 17; 364(6441):681-685. Smaligo AJ, Swain M, Quintana JC, Tan MF, Kim DA, Kwon O. PMID: 31097667; PMCID: PMC6625654.
      View in: PubMed   Mentions: 14     Fields:    
    10. Discussion Addendum for: Phosphine-Catalyzed [4 + 2] Annulation: Synthesis of Ethyl 6-Phenyl-1-tosyl-1,2,5,6-tetrahydropyridine-3-carboxylate. Organic Synth. 2019; 96:110-123. Shaikh AC, Kwon O. PMID: 31736515; PMCID: PMC6857787.
      View in: PubMed   Mentions: 1  
    11. Chiral aminophosphines derived from hydroxyproline and their application in allene-imine [4 + 2] annulation. J Antibiot (Tokyo). 2019 06; 72(6):389-396. Khong SN, Xie C, Wang X, Tan H, Kwon O. PMID: 30940911; PMCID: PMC6599608.
      View in: PubMed   Mentions: 1     Fields:    Translation:Cells
    12. Catalytic Enantioselective Synthesis of Guvacine Derivatives through [4 + 2] Annulations of Imines with α-Methylallenoates. Org Lett. 2018 10 05; 20(19):6089-6093. Xu Q, Dupper NJ, Smaligo AJ, Fan YC, Cai L, Wang Z, Langenbacher AD, Chen JN, Kwon O. PMID: 30246538; PMCID: PMC6173629.
      View in: PubMed   Mentions: 5     Fields:    Translation:Cells
    13. Synthesis of Cyclic β-Silylalkenyl Triflates via an Alkenyl Cation Intermediate. Org Lett. 2018 09 07; 20(17):5474-5477. Lee CJ, Swain M, Kwon O. PMID: 30118234; PMCID: PMC6133754.
      View in: PubMed   Mentions:    Fields:    Translation:Cells
    14. Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene-Imine [3 + 2] Annulation. ACS Catal. 2018 Jun 01; 8(6):5188-5192. Smaligo AJ, Vardhineedi S, Kwon O. PMID: 30393576; PMCID: PMC6208446.
      View in: PubMed   Mentions: 7  
    15. Bridged [2.2.1] bicyclic phosphine oxide facilitates catalytic γ-umpolung addition-Wittig olefination. Chem Sci. 2018 Feb 21; 9(7):1867-1872. Zhang K, Cai L, Yang Z, Houk KN, Kwon O. PMID: 29732112; PMCID: PMC5909331.
      View in: PubMed   Mentions: 13  
    16. Intramolecular Crossed [2+2] Photocycloaddition through Visible Light-Induced Energy Transfer. J Am Chem Soc. 2017 07 26; 139(29):9807-9810. Zhao J, Brosmer JL, Tang Q, Yang Z, Houk KN, Diaconescu PL, Kwon O. PMID: 28683547.
      View in: PubMed   Mentions: 13     Fields:    Translation:Cells
    17. Jagged1 Instructs Macrophage Differentiation in Leprosy. PLoS Pathog. 2016 08; 12(8):e1005808. Kibbie J, Teles RM, Wang Z, Hong P, Montoya D, Krutzik S, Lee S, Kwon O, Modlin RL, Cruz D. PMID: 27532668; PMCID: PMC4988718.
      View in: PubMed   Mentions: 15     Fields:    Translation:HumansCells
    18. Catalytic Asymmetric Total Synthesis of (-)-Actinophyllic Acid. J Am Chem Soc. 2016 Mar 16; 138(10):3298-301. Cai L, Zhang K, Kwon O. PMID: 26910382; PMCID: PMC4920546.
      View in: PubMed   Mentions: 14     Fields:    Translation:Cells
    19. Nanoformulation of Geranylgeranyltransferase-I Inhibitors for Cancer Therapy: Liposomal Encapsulation and pH-Dependent Delivery to Cancer Cells. PLoS One. 2015; 10(9):e0137595. Lu J, Yoshimura K, Goto K, Lee C, Hamura K, Kwon O, Tamanoi F. PMID: 26352258; PMCID: PMC4564137.
      View in: PubMed   Mentions: 2     Fields:    Translation:HumansCells
    20. Phosphine-Mediated Iterative Arene Homologation Using Allenes. J Am Chem Soc. 2015 Sep 09; 137(35):11258-61. Zhang K, Cai L, Jiang X, Garcia-Garibay MA, Kwon O. PMID: 26295504; PMCID: PMC4915745.
      View in: PubMed   Mentions: 6     Fields:    
    21. Stereoselective Syntheses of α,β-Unsaturated γ-Amino Esters Through Phosphine-Catalyzed γ-Umpolung Additions of Sulfonamides to γ-Substituted Allenoates. Tetrahedron Lett. 2015 Jun 03; 56(23):3273-3276. Zhou QF, Zhang K, Kwon O. PMID: 26041942; PMCID: PMC4450090.
      View in: PubMed   Mentions: 5     Fields:    
    22. Synthesis of Functionalized Alkylidene Indanes and Indanones through Tandem Phosphine-Palladium Catalysis. Org Lett. 2015 May 01; 17(9):2058-61. Fan YC, Kwon O. PMID: 25871577; PMCID: PMC4489696.
      View in: PubMed   Mentions: 2     Fields:    Translation:Cells
    23. Resveratrol and para-coumarate serve as ring precursors for coenzyme Q biosynthesis. J Lipid Res. 2015 Apr; 56(4):909-19. Xie LX, Williams KJ, He CH, Weng E, Khong S, Rose TE, Kwon O, Bensinger SJ, Marbois BN, Clarke CF. PMID: 25681964; PMCID: PMC4373747.
      View in: PubMed   Mentions: 19     Fields:    Translation:HumansAnimalsCells
    24. Functionalized α,α-dibromo esters through Claisen rearrangements of dibromoketene acetals. Org Lett. 2015 Feb 20; 17(4):1054-7. Dupper NJ, Kwon O. PMID: 25671693; PMCID: PMC4482617.
      View in: PubMed   Mentions: 1     Fields:    Translation:Cells
    25. Mitochondrial Ca(2+) uptake by the voltage-dependent anion channel 2 regulates cardiac rhythmicity. Elife. 2015 Jan 15; 4. Shimizu H, Schredelseker J, Huang J, Lu K, Naghdi S, Lu F, Franklin S, Fiji HD, Wang K, Zhu H, Tian C, Lin B, Nakano H, Ehrlich A, Nakai J, Stieg AZ, Gimzewski JK, Nakano A, Goldhaber JI, Vondriska TM, Hajnóczky G, Kwon O, Chen JN. PMID: 25588501; PMCID: PMC4293673.
      View in: PubMed   Mentions: 36     Fields:    Translation:AnimalsCells
    26. Hydroxyproline-derived pseudoenantiomeric [2.2.1] bicyclic phosphines: asymmetric synthesis of (+)- and (-)-pyrrolines. J Am Chem Soc. 2014 Aug 27; 136(34):11890-3. Henry CE, Xu Q, Fan YC, Martin TJ, Belding L, Dudding T, Kwon O. PMID: 25099350; PMCID: PMC4151783.
      View in: PubMed   Mentions: 23     Fields:    Translation:Cells
    27. Phosphine-Initiated General-Base-Catalyzed Quinolone Synthesis. Asian J Org Chem. 2014 Apr; 3(4):453-457. Khong S, Kwon O. PMID: 26207200; PMCID: PMC4509642.
      View in: PubMed   Mentions: 3  
    28. Advances in nucleophilic phosphine catalysis of alkenes, allenes, alkynes, and MBHADs. Chem Commun (Camb). 2013 Dec 25; 49(99):11588-619. Fan YC, Kwon O. PMID: 24196409; PMCID: PMC3896345.
      View in: PubMed   Mentions: 39     Fields:    Translation:Cells
    29. Origins of 1,6-stereoinduction in torquoselective 6π electrocyclizations. J Am Chem Soc. 2013 Mar 27; 135(12):4878-83. Patel A, Barcan GA, Kwon O, Houk KN. PMID: 23448287; PMCID: PMC3632451.
      View in: PubMed   Mentions: 3     Fields:    Translation:Cells
    30. A torquoselective 6π electrocyclization approach to reserpine alkaloids. Org Lett. 2012 Nov 02; 14(21):5388-91. Barcan GA, Patel A, Houk KN, Kwon O. PMID: 23039026; PMCID: PMC3488149.
      View in: PubMed   Mentions: 16     Fields:    Translation:Cells
    31. One-pot phosphine-catalyzed syntheses of quinolines. J Org Chem. 2012 Sep 21; 77(18):8257-67. Khong S, Kwon O. PMID: 22928667; PMCID: PMC3459651.
      View in: PubMed   Mentions: 8     Fields:    Translation:Cells
    32. Total synthesis of (±)-hirsutine: application of phosphine-catalyzed imine-allene [4 + 2] annulation. Org Lett. 2012 Sep 07; 14(17):4634-7. Villa RA, Xu Q, Kwon O. PMID: 22920858; PMCID: PMC3439149.
      View in: PubMed   Mentions: 11     Fields:    Translation:AnimalsCells
    33. Phosphine/palladium-catalyzed syntheses of alkylidene phthalans, 3-deoxyisoochracinic acid, isoochracinic acid, and isoochracinol. Org Lett. 2012 Jul 06; 14(13):3264-7. Fan YC, Kwon O. PMID: 22721256; PMCID: PMC3391320.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    34. Chiral aminophosphines as catalysts for enantioselective double-Michael indoline syntheses. Molecules. 2012 May 11; 17(5):5626-50. Khong SN, Kwon O. PMID: 22580397; PMCID: PMC4091971.
      View in: PubMed   Mentions: 6     Fields:    Translation:Cells
    35. Phosphine-catalyzed intramolecular γ-umpolung addition of α-aminoalkylallenic esters: facile synthesis of 3-carbethoxy-2-alkyl-3-pyrrolines. Chem Commun (Camb). 2012 May 28; 48(43):5373-5. Andrews IP, Blank BR, Kwon O. PMID: 22526463; PMCID: PMC4128507.
      View in: PubMed   Mentions: 8     Fields:    Translation:Cells
    36. Enantioselective total synthesis of (+)-ibophyllidine via an asymmetric phosphine-catalyzed [3 + 2] annulation. Chem Sci. 2012 Jan 01; 3(8):2510-2514. Andrews IP, Kwon O. PMID: 22798981; PMCID: PMC3393134.
      View in: PubMed   Mentions: 18  
    37. PHOSPHINE-CATALYZED [3 + 2] ANNULATION: SYNTHESIS OF ETHYL 5-(tert-BUTYL)-2-PHENYL-1-TOSYL-3-PYRROLINE-3-CARBOXYLATE. Organic Synth. 2012; 2012. Andrews IP, Kwon O. PMID: 25484470; PMCID: PMC4257132.
      View in: PubMed   Mentions: 2  
    38. Identification and characterization of mechanism of action of P61-E7, a novel phosphine catalysis-based inhibitor of geranylgeranyltransferase-I. PLoS One. 2011; 6(10):e26135. Chan LN, Fiji HD, Watanabe M, Kwon O, Tamanoi F. PMID: 22028818; PMCID: PMC3196516.
      View in: PubMed   Mentions: 11     Fields:    Translation:HumansAnimalsCells
    39. Phosphine-initiated general base catalysis: facile access to benzannulated 1,3-diheteroatom five-membered rings via double-Michael reactions of allenes. Org Lett. 2011 Oct 21; 13(20):5420-3. Szeto J, Sriramurthy V, Kwon O. PMID: 21932819; PMCID: PMC3193576.
      View in: PubMed   Mentions: 14     Fields:    Translation:Cells
    40. Phosphine-catalyzed [4+2] annulations of 2-alkylallenoates and olefins: synthesis of multisubstituted cyclohexenes. Chem Asian J. 2011 Aug 01; 6(8):2101-6. Tran YS, Martin TJ, Kwon O. PMID: 21739609; PMCID: PMC4122298.
      View in: PubMed   Mentions: 11     Fields:    Translation:Cells
    41. Diversity-oriented synthesis based on the DPPP-catalyzed mixed double-Michael reactions of electron-deficient acetylenes and β-amino alcohols. Molecules. 2011 May 05; 16(5):3802-25. Fan YC, Kwon O. PMID: 21546881; PMCID: PMC4126835.
      View in: PubMed   Mentions: 10     Fields:    Translation:Cells
    42. Phosphine-catalyzed β'-umpolung addition of nucleophiles to activated α-alkyl allenes. Org Lett. 2011 May 20; 13(10):2586-9. Martin TJ, Vakhshori VG, Tran YS, Kwon O. PMID: 21491870; PMCID: PMC3094471.
      View in: PubMed   Mentions: 9     Fields:    Translation:Cells
    43. Diversity through phosphine catalysis identifies octahydro-1,6-naphthyridin-4-ones as activators of endothelium-driven immunity. Proc Natl Acad Sci U S A. 2011 Apr 26; 108(17):6769-74. Cruz D, Wang Z, Kibbie J, Modlin R, Kwon O. PMID: 21383121; PMCID: PMC3084088.
      View in: PubMed   Mentions: 17     Fields:    Translation:HumansCells
    44. Aplexone targets the HMG-CoA reductase pathway and differentially regulates arteriovenous angiogenesis. Development. 2011 Mar; 138(6):1173-81. Choi J, Mouillesseaux K, Wang Z, Fiji HD, Kinderman SS, Otto GW, Geisler R, Kwon O, Chen JN. PMID: 21307094; PMCID: PMC3042872.
      View in: PubMed   Mentions: 26     Fields:    Translation:HumansAnimalsCells
    45. Diversity through a branched reaction pathway: generation of multicyclic scaffolds and identification of antimigratory agents. Chemistry. 2011 Jan 10; 17(2):649-54. Wang Z, Castellano S, Kinderman SS, Argueta CE, Beshir AB, Fenteany G, Kwon O. PMID: 21207585; PMCID: PMC3045630.
      View in: PubMed   Mentions: 15     Fields:    Translation:HumansCells
    46. Tandem 6pi-electrocyclization and cycloaddition of nitrodienes to yield multicyclic nitroso acetals. J Am Chem Soc. 2010 Jul 07; 132(26):8876-7. Creech GS, Kwon O. PMID: 20557050; PMCID: PMC2903206.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    47. Equilibrium between a vinylogous ylide and a phosphonium dienolate zwitterion: vinylogous Wittig olefination versus vinylogous aldol-type reaction. Tetrahedron. 2010 Jun; 66(26):4760-4768. Khong SN, Tran YS, Kwon O. PMID: 21359169; PMCID: PMC3043383.
      View in: PubMed   Mentions: 8     Fields:    
    48. Diphosphine-catalyzed mixed double-Michael reaction: a unified synthesis of indolines, dihydropyrrolopyridines, benzimidazolines, tetrahydroquinolines, tetrahydroisoquinolines, dihydrobenzo-1,4-oxazines, and dihydrobenzo-3,1-oxazines. Org Lett. 2010 Mar 05; 12(5):1084-7. Sriramurthy V, Kwon O. PMID: 20143856; PMCID: PMC2835628.
      View in: PubMed   Mentions: 16     Fields:    Translation:Cells
    49. Phosphine-promoted [3 + 3] annulations of aziridines with allenoates: facile entry into highly functionalized tetrahydropyridines. J Am Chem Soc. 2009 May 13; 131(18):6318-9. Guo H, Xu Q, Kwon O. PMID: 19374356; PMCID: PMC2749062.
      View in: PubMed   Mentions: 23     Fields:    Translation:Cells
    50. In vivo antitumor effect of a novel inhibitor of protein geranylgeranyltransferase-I. Mol Cancer Ther. 2009 May; 8(5):1218-26. Lu J, Chan L, Fiji HD, Dahl R, Kwon O, Tamanoi F. PMID: 19417142; PMCID: PMC2888841.
      View in: PubMed   Mentions: 41     Fields:    Translation:HumansAnimalsCells
    51. Highly efficient palladium-catalyzed hydrostannation of ethyl ethynyl ether. Tetrahedron Lett. 2008 Dec 08; 49(50):7097-7099. Andrews IP, Kwon O. PMID: 20011027; PMCID: PMC2598759.
      View in: PubMed   Mentions:    Fields:    
    52. Theory-Guided Design of Brønsted Acid-Assisted Phosphine Catalysis: Synthesis of Dihydropyrones from Aldehydes and Allenoates. Tetrahedron. 2008 Jul 14; 64(29):6935-6942. Creech GS, Zhu XF, Fonovic B, Dudding T, Kwon O. PMID: 19606204; PMCID: PMC2597818.
      View in: PubMed   Mentions: 11     Fields:    
    53. Inhibitors of protein geranylgeranyltransferase I and Rab geranylgeranyltransferase identified from a library of allenoate-derived compounds. J Biol Chem. 2008 Apr 11; 283(15):9571-9. Watanabe M, Fiji HD, Guo L, Chan L, Kinderman SS, Slamon DJ, Kwon O, Tamanoi F. PMID: 18230616; PMCID: PMC2442295.
      View in: PubMed   Mentions: 35     Fields:    Translation:HumansAnimalsCells
    54. Alcohol-assisted phosphine catalysis: one-step syntheses of dihydropyrones from aldehydes and allenoates. Org Lett. 2008 Feb 07; 10(3):429-32. Creech GS, Kwon O. PMID: 18173275; PMCID: PMC2532593.
      View in: PubMed   Mentions: 21     Fields:    Translation:Cells
    55. Bisphosphine-catalyzed mixed double-Michael reactions: asymmetric synthesis of oxazolidines, thiazolidines, and pyrrolidines. J Am Chem Soc. 2007 Oct 31; 129(43):12928-9. Sriramurthy V, Barcan GA, Kwon O. PMID: 17924625; PMCID: PMC2536693.
      View in: PubMed   Mentions: 26     Fields:    Translation:Cells
    56. Phosphine-catalyzed [4 + 2] annulation: synthesis of cyclohexenes. J Am Chem Soc. 2007 Oct 24; 129(42):12632-3. Tran YS, Kwon O. PMID: 17914823; PMCID: PMC2586001.
      View in: PubMed   Mentions: 38     Fields:    Translation:Cells
    57. Phosphine-catalyzed synthesis of highly functionalized coumarins. Org Lett. 2007 Aug 02; 9(16):3069-72. Henry CE, Kwon O. PMID: 17629288.
      View in: PubMed   Mentions: 27     Fields:    Translation:Cells
    58. Stable tetravalent phosphonium enolate zwitterions. J Am Chem Soc. 2007 May 30; 129(21):6722-3. Zhu XF, Henry CE, Kwon O. PMID: 17488018; PMCID: PMC2535772.
      View in: PubMed   Mentions: 14     Fields:    
    59. Small-molecule inhibitors of protein geranylgeranyltransferase type I. J Am Chem Soc. 2007 May 09; 129(18):5843-5. Castellano S, Fiji HD, Kinderman SS, Watanabe M, Leon Pd, Tamanoi F, Kwon O. PMID: 17439124; PMCID: PMC2543057.
      View in: PubMed   Mentions: 43     Fields:    Translation:HumansCells
    60. An application of the phosphine-catalyzed [4 + 2] annulation in indole alkaloid synthesis: formal syntheses of (+/-)-alstonerine and (+/-)-macroline. Org Lett. 2005 Sep 15; 7(19):4289-91. Tran YS, Kwon O. PMID: 16146409.
      View in: PubMed   Mentions: 34     Fields:    Translation:Cells
    61. Phosphine-catalyzed synthesis of 6-substituted 2-pyrones: manifestation of E/Z-isomerism in the zwitterionic intermediate. Org Lett. 2005 Jul 07; 7(14):2977-80. Zhu XF, Schaffner AP, Li RC, Kwon O. PMID: 15987184.
      View in: PubMed   Mentions: 27     Fields:    
    62. Phosphine-catalyzed synthesis of 1,3-dioxan-4-ylidenes. Org Lett. 2005 Mar 31; 7(7):1387-90. Zhu XF, Henry CE, Wang J, Dudding T, Kwon O. PMID: 15787513.
      View in: PubMed   Mentions: 25     Fields:    
    63. Synthesis of the [5-7-6] tricyclic core of guanacastepene A via an intramolecular Mukaiyama aldol reaction. Org Lett. 2003 May 29; 5(11):1923-6. Du X, Chu HV, Kwon O. PMID: 12762687.
      View in: PubMed   Mentions: 4     Fields:    Translation:Cells
    64. An expedient phosphine-catalyzed [4 + 2] annulation: synthesis of highly functionalized tetrahydropyridines. J Am Chem Soc. 2003 Apr 23; 125(16):4716-7. Zhu XF, Lan J, Kwon O. PMID: 12696883.
      View in: PubMed   Mentions: 56     Fields:    Translation:Cells
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